CHM402 Solutions

CHM402 Tma Solutions

For which of the following molecules would you expect the infrared active fundamentals to be Raman inactive and vice versa?

nitrogen(IV) oxide

fluorobenzene

—>> benzene

fluoroethene

Which of these is not found in a Raman spectrometer?

lenses and mirrors

monochromator

—>> osciloscope

detector

The wavelength of an absorption is 495 nm. In what part of the electromagnetic spectrum does this lie?

Microwave.

infra-red

—>> UV-Visible

Radiowave

A photon of wavenumber \(100 cm^{-1}\) has a wavelength of

1 m

—>> 1 mm

1000 nm

100 m

Which section of the electromagnetic spectrum is responsible for molecular vibration?

—>> Infra-red

Ultraviolet

Microwave

gamma rays

Identify the most intense line

Raman line

—>> Rayleigh line

Stokes’ line

antiStokes’ line

How many normal modes of vibration are there for \(C_{60}\) ?

—>> 174

180

60

175

Which is associated with elastic scattering?

Raman line

—>> Rayleigh line

Stokes’ line

antiStokes’ line

Which of these is not an in-plane vibrational mode?

stretching

—>> twisting

scissoring

rocking

Which statement is true?

symmetric stretching require higher energy than asymmetric stretching

—>> bending vibrations require lower energy than stretching

bending vibrations require higher energy that stretching

both bending and stretching require similar energies

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