NATIONAL OPEN UNIVERSITY OF NIGERIA
14/16 AHMADU BELLO WAY, VICTORIA ISLAND, LAGOS
SCHOOL OF SCIENCE AND TECHNOLOGY
MARCH/APRIL 2014 EXAMINATION
COURSE CODE: CHM413
COURSE TITLE: ANALYTICAL CHEMISTRY 11
TIME ALLOWED: 2HOURS
INSTRUCTION: Six questions to answer four(Each question carriers a total 17marks)
Question 1
a) Distinguish between random and systematic errors (7marks)
b) Define the following terms:
i) Random error ii) Confidence limits iii) Accuracy iv) Precision (2mark each; total of 10marks)
Question 2
The result of the concentration of zinc metal (mg/L) in soil of a waste dump is presented as follows:
178.0 125.68 100.50147.50 111.16 95.46 143.20 98.89
Calculate:
- i) Mean (3marks)
- ii) Median (4 marks)
iii) Standard deviation (5 marks)
- iv) The 95% confidence limits for the true mean. (5 marks)
Question 3
- a) State two types of glass membrane electrode (5 marks)
- b) A solution is 10-3M in Cr2O7-2 and 10-2M inCr3+. If the pH is 2.0, what is the potential of the half reaction? (8marks)
Question 4
- a) Discuss the factors that affect the conductance of electrolyte solutions. (8marks)
- b) Differentiate between thin layer chromatography and column chromatography. (9marks)
Question 5
Write short notes on the following:
- a) Electrochemical deposition b) Particulate radiation c) Electromagnetic radiation
- d) Ion exchange techniques. (4mark each; total of 17marks)
Questions 6
a)State theKohlrausch law of independent migration of ions (3marks)
- b) Briefly explain the two application of Kohlrausch law of independent migration of ions (5 marks)
- c) For acetic acid (HAc), Lo = 390.6 ohm-1 cm2 mol-1, while at a concentration of 0.003441 mol dm-3, L = 27.19 ohm-1 cm2 mol-1. What is the degree of disassociation, the concentration of each species, and the equilibrium constant? (9 marks)
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